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ruthenium tetroxide : ウィキペディア英語版
ruthenium tetroxide

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Ruthenium tetroxide (''Ruthenium(VIII) oxide'') is the inorganic compound with the formula RuO4. It is a colourless liquid but samples are typically black due to impurities. As expected for a charge-neutral symmetrical oxide, it is quite volatile. The analogous OsO4 is more widely used and better known. One of the few solvents in which it forms stable solutions is CCl4.
== Preparation ==
RuO4 is prepared by oxidation of ruthenium(III) chloride with NaIO4.
:8 Ru3+(aq) + 5 IO4(aq) + 12 H2O(l) → 8 RuO4(s) + 5 I(aq) + 24 H+(aq)

In typical reactions featuring RuO4 as the oxidant, many forms of ruthenium usefully serve as precursors to RuO4, such as oxide hydrates or hydrated chloride.

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